北京市典型排放源PM_(2.5)成分谱研究

为了建立和完善北京市PM_(2.5)本地化源谱,对北京市11类排放源PM_(2.5)进行采集,并测定其26种组分,分析了不同排放源源谱的组分特征.结果表明,在有组织排放源中,燃煤电厂PM_(2.5)中OC和Si含量很高,占PM_(2.5)的质量分数分别为8.56%和6.19%(平均值),而供热/工业锅炉排放PM_(2.5)中则是SO_4~(2-)(占48.38%)和OC(11.0%)比例最高,水泥窑炉PM_(2.5)中OC(7.12%)、Ca(4.81)和Si(4.41%)占有较大比例;垃圾焚烧排放的PM_(2.5)中Si、Ca、K和SO_4~(2-)均较高,分别占8.15%、9.36%、7.17%和6.79%,且Cl~-含量(2.5%)高于其他所有源,生物质燃烧源PM_(2.5)中OC(21.7%)、Si(6.75%)、Ca(6.15%)较为丰富,餐饮源PM_(2.5)中OC(19.44%)、SO_4~(2-)(5.76%)和K(3.11%)含量均较高;无组织开放源中,道路扬尘和土壤风沙PM_(2.5)化学组分含量变化较为一致,均是Si(分别为16.8%和9.3%)和OC(分别为8.89%和6.61%)最高,建筑水泥尘PM_(2.5)中Ca(17.46%)含量高于其他源;流动排放源PM_(2.5)中OC、EC比例最高,其中,重型柴油车的OC(29.79%)与EC(26.5%)排放比例相当,而轻型汽油车OC排放占有绝对优势(占75%).本文通过对比国内外部分排放源PM_(2.5)成分谱的差异,指出不同区域相同源类排放的PM_(2.5)化学组分差异较大,在应用受体模型中的化学质量平衡模型(CMB)判断受体颗粒物来源时,应基于本地的排放源成分谱,以避免较大的误差.     

Kinetics characteristics of coal low-temperature oxidation in oxygen-depleted air

The longwall gob (mined-out) area is one of the main places that are prone to coal spontaneous combustion and most of the residual coal in it is in oxygen-depleted air as it is a semi-enclosed space. A DSC (Differential scanning calorimetry) test system was designed to accurately test the heat generation of coal oxidation in different oxygen concentration atmosphere, based on which the kinetics parameters (activation energy and pre-exponential factor) of coal low-temperature oxidation in oxygen-depleted air were solved out. The results show that the kinetics parameters present obvious stage features and the lower the oxygen concentration is, the smaller is the difference of the kinetics parameters that in different oxidation stages. When the oxygen concentration is lower than 5% and 3% for jet coal and meagre coal respectively, the kinetics parameters of slow oxidation start to be greater than that of rapid oxidation. Both in the slow oxidation and rapid oxidation stage, with the decrease of oxygen concentration, kinetics parameters present significant decline on the whole while in different oxygen concentration range, the decline rate is different. It's concluded that when assessing the residual coal's self-heating risk, we need to use the corresponding kinetics parameters of coal oxidation in the oxygen concentration of the location where the residual coal is and the safety factor will be greater to only use the kinetics parameters of coal oxidation in slow oxidation stage. This study is of great significance for the assessment and control of the self-heating risk of coal that in different oxygen concentration atmospheres of the longwall gob areas.     

Flame behaviors and pressure characteristics of vented dust explosions at elevated static activation overpressures

Dust explosion venting experiments were performed using a 20-L spherical chamber at elevated static activation overpressures larger than 1 bar. Lycopodium dust samples with mean diameter of 70 μm and electric igniters with 0.5 KJ ignition energy were used in the experiments. Explosion overpressures in the chamber and flame appearances near the vent were recorded simultaneously. The results indicated that the flame appeared as the under-expanded free jet with shock diamonds, when the overpressure in the chamber was larger than the critical pressure during the venting process. The flame appeared as the normal constant-pressure combustion when the pressure venting process finished. Three types of venting processes were concluded in the experiments: no secondary flame and no secondary explosion, secondary flame, secondary explosion. The occurrence of the secondary explosions near the vent was related to the vent diameter and the static activation overpressure. Larger diameters and lower static activation overpressures were beneficial to the occurrence of the secondary explosions. In current experiments, the secondary explosions only occurred at the following combinations of the vent diameter and the static activation overpressure: 40 mm and 1.2 bar, 60 mm and 1.2 bar, 60 mm and 1.8 bar.     

露天矿山岩质边坡台阶的平台宽度优化

矿山发生局部破坏的边界条件主要是由台阶的几何特征所决定,台阶边坡几何特征主要有台阶坡面角、台阶高度、台阶的平台宽度和台阶组合4要素。在对整体边坡角优化的同时,同样需要对台阶的宽度进行优化。通过分析台阶边坡特征,计算出不同规模破坏的边界条件,进而对矿山台阶的宽度进行优化。通过对一个矿山边坡算例的优化分析,在不改变整体边坡角的前提下,对台阶宽度进行优化,可以避免某些大规模的台阶破坏可能,提高矿山边坡的稳定性。     

贵州织金蒙家大坡地下水水化学特征分析

通过对贵州织金蒙家大坡地下水水化学指标进行分析。结果表明,研究区地下水Ca2+受环境影响最小、空间变异性最小,Na+受环境影响最大、空间变异性最大;各阴阳离子含量与TDS含量呈显著正相关关系,其相关性依次为:Ca2+SO2-4Mg2+Cl-HCO-3K+Na+;TDS含量的增加主要受SO2-4离子的影响,总硬度的变化主要受Ca2+的影响;地下水成分主要来自于碳酸盐矿物的溶解,其次是硫酸盐、含硫矿物、硅酸盐矿物以及盐岩的溶解,地下水类型主要向SO4·HCO3-Ca型和HCO3·SO4-Ca型转化。     

连续型空间故障树中因素重要度分布的定义与认知

为了解工作环境条件因素对系统故障概率的影响的特征,同时丰富连续型空间故障树(CSFT)的理论框架,提出因素重要度分布的概念。因素重要度分布从经典故障树的概率重要度发展而来,目的是研究系统所处环境因素变化导致系统可靠性变化的程度。给出元件和系统的因素重要度分布概念、公式及所需基础数据,并分析因素重要度分布的正负分布特点。使用该概念研究元件X1和系统T的因素t重要度分布和因素c重要度分布。结果表明:在不同环境中,对于因素t或c变化影响元件或系统的故障概率变化程度是不同的。因素重要度分布有效地表达了t和c对元件或系统的故障概率影响特征。     

烧结砖中重金属释放特性研究

通过向黏土中添加重金属试剂,模拟煅烧试验制作烧结砖.采用酸消解试验研究烧结砖中重金属的总量,采用欧盟NEN7371方法测试烧结砖中重金属的有效释放量,采用NEN7375方法进行块状烧结砖浸出试验,研究烧结砖样品中Cr、Ni、As、Cd和Pb的释放特性.结果表明:烧结砖中重金属的有效释放量低于总量,释放率从大到小为Cd、As、Pb、Ni、Cr;在块状浸出过程中,Cr、Ni、As累积释放量达到平衡的时间为16 d,Pb为4d,而Cd的累积释放量一直有上升的趋势;Cr、Ni、As的释放机理主要为扩散控制,Cd为溶解作用,Pb为表面冲刷作用;5种重金属释放速率从大到小为Ni、Cr、Pb、As、Cd.     

基于数值模拟的公交车火灾发展过程及特性研究

采用数值模拟方法研究典型型号公交车的火灾发展过程,探讨车门打开对火情发展和人员逃生的影响.通过描述火源、公交车的结构及其内饰物的属性,研究车厢内关键位置的温度分布、能见度及CO和O2体积分数的变化规律,以揭示公交车的火灾发展、烟气运动过程及对人员安全逃生的影响.结果表明:车门打开后由于供氧充足,明显加速了火势的蔓延和烟气扩散,并使得燃烧温度显著提高;打开车门后20 s内,车门附近能见度和O2体积分数显著增高,CO体积分数有所降低,是乘客逃生的关键时间.     

Immobilization of lead in anthropogenic contaminated soils using phosphates with/without oxalic acid

Understanding the effects of oxalic acid(OA) on the immobilization of Pb(Ⅱ) in contaminated soils by phosphate materials, has considerable benefits for risk assessment and remediation strategies for the soil. A series of phosphate amendments with/without oxalic acid were applied to two anthropogenic contaminated soils. We investigated the immobilization of Pb(Ⅱ) by KH2PO4, phosphate rock(PR), activated phosphate rock(APR) and synthetic hydroxyapatite(HAP) at different phosphate:Pb(P:Pb) molar ratios(0, 0.6, 2.0 and 4.0) in the presence/absence of 50 mmol oxalic acid/kg soil, respectively. The effects of treatments were evaluated using single extraction with deionized water or Ca Cl2, Community Bureau of Reference(BCR) sequential extraction and toxicity characteristic leaching procedure(TCLP)methods. Our results showed that the concentration of water extractable, exchangeable and TCLP-Pb all decreased with incubation time. The concentration of water-extractable Pb after120 days was reduced by 100% when soils were amended with APR, HAP and HAP + OA, and the TCLP-Pb was 5 mg/L for the red soil at P:Pb molar ratio 4.0. Water-soluble Pb could not be detected and the TCLP-Pb was 5 mg/L at all treatments applied to the yellow-brown soil. BCR results indicated that APR was most effective, although a slight enhancement of water-soluble phosphate was detected at the P:Pb molar ratio 4.0 at the beginning of incubation. Oxalic acid activated phosphates, and so mixing insoluble phosphates with oxalic acid may be a useful strategy to improve their effectiveness in reducing Pb bioavailability.     

分段变速加载对含瓦斯突出煤力学特性影响试验研究

为探究采动应力变化对含瓦斯突出煤力学特性的影响，利用RLW-500G煤岩三轴蠕变-渗流试验系统，对新景矿含瓦斯突出煤进行了不同围压和瓦斯压力下的常规三轴和分段变速加载力学试验。结果表明:煤样在2种应力路径下的全应力应变曲线均可分为压密、线弹性、塑性变形、应力跌落和残余应力5个阶段；随着围压的升高或者瓦斯压力的降低，煤体在2种应力路径下的强度和弹性模量均增大；相较于常规三轴，煤体在分段变速加载路径下的强度普遍增大，峰值轴向应变、峰值环向应变绝对值和峰值体积应变绝对值也普遍增大，失稳破坏瞬间应力跌落和能量释放更加剧烈。Mohr-Coulomb强度准则仍然适用于分段变速加载条件下的含瓦斯突出煤，该研究对于认识煤与瓦斯突出的发生机制具有一定的指导意义。